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Introduction to metal and non-metal oxides

Key points

  • Metals and non-metals can react with oxygen to make compounds called oxides.
  • Metal oxides act as bases. This means they can neutralise an acid.
  • Non-metal oxides usually dissolve in water to make acidic solutions.
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A video about oxidation reactions

A video that shows what happens when metals and non-metals are combined with oxygen

List some of the typical properties of metals.

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Metals in the periodic table

Metals are found on the left and in the middle of the

A line of steps underneath boron (B) can be drawn to divide the table into metals and non-metals.

The periodic table showing metals on the left of the periodic table, and non-metals on the right
Figure caption,
Metals are on the left of the periodic table, and non-metals are on the right
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Oxides

are substances made of two or more types of chemically bonded together. All are compounds, and contain a single element bonded with oxygen.

For example:

  • magnesium oxide has the chemical formula MgO, and contains only magnesium (Mg) and oxygen (O)
  • sodium oxide has the formula Naâ‚‚O and contains only sodium (Na) and oxygen
  • aluminium oxide has the formula Alâ‚‚O₃ and contains only aluminium (Al) and oxygen
Three question marks

Did you know?

Some chemical formulas contain little numbers called ‘subscripts’. They represent the number of atoms of each element in the formula. For example, CO₂ contains one carbon atom and two oxygen atoms.

Three question marks

When oxides are named they include a prefix at the beginning of the word ‘oxide’. These prefixes show how many oxygen atoms are in the oxide.

For example:

  • carbon **mon**oxide has the formula CO, it has one oxygen atom
  • carbon **di**oxide has the formula COâ‚‚, it has two oxygen atoms
  • sulfur **tri**oxide has the formula SO₃, it has three oxygen atoms

The prefixes match up to the number of oxygen atoms.

The molecules of three oxides: carbon monoxide (CO), carbon dioxide (CO2) and sulfur trioxide (SO3).
Figure caption,
The molecular structure of three non-metal oxides

Silicon has the symbol Si. What is the formula of silicon dioxide?

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Forming oxides

When an element reacts with oxygen a chemical bond is formed. The compound formed is called an oxide. This can be written as a .

Chemical equations can be written as word equations or symbol equations. For example, the word equations:

calcium + oxygen → calcium oxide

carbon + oxygen → carbon dioxide

Or the symbol equations:

Ca + O₂ → CaO

C + O₂ → CO₂

Some elements will react with oxygen in the air at room temperature. For example, sodium reacts with the oxygen in air to produce a white coating of sodium oxide. When the sodium is cut, the fresh shiny sodium is visible.

Magnesium burning with a bright light
Image caption,
Magnesium burning with a bright light

Lots of are less than sodium. They require heating in a to make the reaction occur.

For example, when a strip of magnesium is heated in a Bunsen burner a bright white flame is seen. The magnesium reacts with oxygen in the air. The shiny grey magnesium strip changes to a white powder called magnesium oxide.

Learn more about making a reactivity series in this guide.

Magnesium burning with a bright light
Image caption,
Magnesium burning with a bright light

When magnesium is heated with a Bunsen burner it forms magnesium oxide. Where do the oxygen atoms come from?

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Properties of metal and non-metal oxides

Metal oxides

Metal oxides are solids. One of the properties of metal oxides is that they act as . This means that they are able to , producing a salt plus water.

Some metal oxides react with water to make an alkali, a which has a higher than 7. Alkalis also neutralise acids to produce a salt plus water.

For example, sodium is burned to make sodium oxide. Sodium oxide is a base because it can neutralise an acid. Sodium oxide can be reacted with water to produce a sodium hydroxide solution. The pH of this solution would be 14, which shows it is an alkali.

sodium oxide + water → sodium hydroxide

Base + water → alkali

Non-metal oxides

Non-metal oxides are often gases. One of the properties of most non-metal oxides is that they dissolve in and react with water, producing which are . This means the solutions have pH values which are lower than 7.

For example, sulfur burns in oxygen to produce sulfur dioxide. If is squirted into the jar (containing the sulfur dioxide) it immediately turns red which shows a pH of 1.

This tells us sulfur dioxide is an acidic gas.

A chart showing the pH scale and foods and liquids which have that pH, for example pure water is neutral 7, a banana is 5, and bleach is 12
Figure caption,
Different everyday items have different pH values

Find out more about the pH scale in this guide.

An oxide sample is tested and found to have a pH of 3. What type of element is present in the oxide?

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Metal oxides act as bases

Metal oxides act as bases. Bases are substances which can neutralise acids. When a base reacts with an acid it produces a salt and water.

acid + base → salt + water

The specific salt produced depends on which acid and base react together.

For example, copper oxide is reacted with sulfuric acid. This produces the salt copper sulfate.

copper oxide + sulfuric acid → copper sulfate + water

CuO + H₂SO₄ → CuSO₄ + H₂O

Blue crystals of copper sulfate
Image caption,
Blue crystals of copper sulfate

Find out more about neutralisation reactions in this guide.

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Working scientifically

Drawing apparatus

The steps to make copper sulfate crystals from copper oxide and sulfuric acid are as follows:

  1. Measure 25 cm³ of sulfuric acid using a measuring cylinder and pour into a beaker.
  2. Warm gently using a Bunsen burner.
  3. Add copper oxide and stir until it dissolves into the acid.
  4. Add more copper oxide until it no longer dissolves.
  5. Filter out the unreacted copper oxide.
  6. Pour the solution (copper sulfate) into an evaporating basin and place this on top of a beaker of water.
  7. Heat the beaker of water using a Bunsen burner until it boils. The steam from the boiling water will warm the evaporating basin containing the copper sulfate solution, causing water to evaporate from the solution. Stop heating when blue crystals start to form around the edge of the copper sulfate solution.
  8. Allow the mixture to cool. The crystals will get larger and the remaining water will evaporate.

A series of scientific diagrams can be drawn to illustrate this method.

A sign which says 'remember'

Keep your diagrams simple.

Always use a sharp pencil and a ruler for your straight lines, and don’t forget to include labels to make your diagram clear.

The two parts of this experiment can be represented by scientific diagrams. Have a look at this scientific diagram showing how to filter the solution.

Filtering the solution
Figure caption,
Filtering the solution

Now have a go at drawing a scientific diagram to represent the heating of the solution. Click below to reveal an example of a diagram to help you.

Find out more about drawing scientific apparatus in this guide.

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Quiz

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Play the Atomic Labs game! game

Try out practical experiments in this KS3 science game.

Play the Atomic Labs game!
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