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Bulk properties

Individual do not have the physical of the substances that contain them. For example, a copper atom cannot electricity, even though a piece of copper can do this. Bulk properties are properties due to many atoms, or acting together.

Melting and boiling points

Chemical are broken or overcome during and boiling. The stronger these bonds are, the higher the and .

Type of substanceExample(s)Bonds brokenRelative bond strength
Simple molecularOxygen, waterIntermolecular forcesWeak
Ionic substanceSodium chlorideIonic bondsStrong
Giant covalentSilicon oxide, diamondCovalent bondsStrong
MetalMagnesium, sodiumMetallic bondsStrong
Type of substanceSimple molecular
Example(s)Oxygen, water
Bonds brokenIntermolecular forces
Relative bond strengthWeak
Type of substanceIonic substance
Example(s)Sodium chloride
Bonds brokenIonic bonds
Relative bond strengthStrong
Type of substanceGiant covalent
Example(s)Silicon oxide, diamond
Bonds brokenCovalent bonds
Relative bond strengthStrong
Type of substanceMetal
Example(s)Magnesium, sodium
Bonds brokenMetallic bonds
Relative bond strengthStrong

Simple substances:

  • have relatively low melting and boiling points
  • are usually gases or liquids at room temperature, or solids that are easily melted

, giant substances and :

  • have relatively high melting and boiling points
  • are usually solids at room temperature

Malleable or brittle

substances can be bent or hammered into shape without shattering. Metals are malleable. When a is applied, layers of metal ions can slide over each other while still being attracted to the ‘sea’ of .

Malleable metal
Figure caption,
Layers of atoms slide over each other when metals are bent or stretched

Ionic substances and giant covalent substances are usually . They shatter when bent or hit because many strong or break at once.

Conducting electricity

A substance can electricity if both:

  • it contains
  • these charged particles are free to move about
Type of substanceConducts electricity? Reason
Simple moleculeNoSimple molecules are not charged
Ionic compoundOnly when molten or dissolvedIons are charged particles, free to move about when the substance is molten or dissolved (not when it is solid)
Giant covalentNoThe individual atoms are not charged
MetalYesContains delocalised electrons, free to move about
Type of substanceSimple molecule
Conducts electricity?No
ReasonSimple molecules are not charged
Type of substanceIonic compound
Conducts electricity?Only when molten or dissolved
ReasonIons are charged particles, free to move about when the substance is molten or dissolved (not when it is solid)
Type of substanceGiant covalent
Conducts electricity?No
ReasonThe individual atoms are not charged
Type of substanceMetal
Conducts electricity?Yes
ReasonContains delocalised electrons, free to move about

Note that , and are covalent substances that do conduct electricity. This is because, like metals, they contain delocalised electrons.